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Oxygen is not a flammable gas but is an oxidiser making other materials ignite more readily and burn more fiercely and quickly. A fire involving an oxygen enriched atmosphere is very dangerous and should be left to professionals. There is no point in having extinguishers over and above what you already have.

More important is good fire prevention measures and that the fire service are aware cylinders are on the premises.

Some advice is here: https://www.airliquidehomecare.co.uk/healthcare-professionals/home-oxygen-safety 

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