Hello David
It is true that Table 4 at 3.20 of The Building Regulations 2010 Fire Safety Approved Document B states the maximum number of persons who can be accommodated by a final exit door of 1050mm width is 220.
However, what if this exit is blocked by fire? At 3.21, 'Calculating exit capacity', the regulations note that 'if a storey or room has two or more exits, it has to be assumed that a fire might prevent the occupants from using one of them'.
This is true of a room with only one exit. If this one and only exit is blocked by fire, what are your contingency plans? Furthermore, even if the exit is not blocked, to assume the maximum number could be safely accommodated is taking a huge risk; depending on the nature of the fire, a panic situation could develop, with a mad rush of 220 people to the door and the possibility of some being crushed.
Have you thought about creating an additional fire exit via a window?
Kind regards
Sally